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young brunette girl posing in a transparent vitreous glass swing chair
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Young Brunette Girl Posing In A Transparent Vitreous Glass Swing Chair

Although the atomic structure of glass shares characteristics of the structure in a supercooled liquid, glass tends to behave as a solid below its glass transition temperature. A supercooled liquid behaves as a liquid, but it is below the freezing point of the material, and in some cases will crystallize almost instantly if a crystal is added as a core. The change in heat capacity at a glass transition and a melting transition of comparable materials are typically of the same order of magnitude, indicating that the change in active degrees of freedom is comparable as well. Both in a glass and in a crystal it is mostly only the vibrational degrees of freedom that remain active, whereas rotational and translational motion is arrested. This helps to explain why both crystalline and non-crystalline solids exhibit rigidity on most experimental time scales.
• Behavior of antique glass
The observation that old windows are sometimes found to be thicker at the bottom than at the top is often offered as supporting evidence for the view that glass flows over a timescale of centuries. The assumption being that the glass was once uniform, but has flowed to its new shape, which is a property of liquid. However, this assumption is incorrect; once solidified, glass does not flow anymore. The reason for the observation is that in the past, when panes of glass were commonly made by glassblowers, the technique used was to spin molten glass so as to create a round, mostly flat and even plate (the crown glass process, described above). This plate was then cut to fit a window. The pieces were not, however, absolutely flat; the edges of the disk became a different thickness as the glass spun. When installed in a window frame, the glass would be placed with the thicker side down both for the sake of stability and to prevent water accumulating in the lead cames at the bottom of the window. Occasionally such glass has been found thinner side down or thicker on either side of the window's edge, the result of carelessness during installation.
Mass production of glass window panes in the early twentieth century caused a similar effect. In glass factories, molten glass was poured onto a large cooling table and allowed to spread. The resulting glass is thicker at the location of the pour, located at the center of the large sheet. These sheets were cut into smaller window panes with nonuniform thickness, typically with the location of the pour centred in one of the panes (known as "bull's-eyes") for decorative effect. Modern glass intended for windows is produced as float glass and is very uniform in thickness.

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